My latest contribution to The A.V. Club is an essay on Alfred Hitchcock Presents and 10 episodes to get you into the series. You may watch them in any order you wish. They used to make TV series that way.
Before you click over, I am tempted to make some sardonic remarks about the "sponsors" at The A.V. Club. But since I don't have Hitchcock's box-office clout, I am bowing to descretion. You are under no obligation to do the same.